Just as water is most familiar to us in the liquid form, so there are substances that are most familiar to us in the gaseous form. In fact, the only gaseous substances that can be said to be familiar to everybody are the gases contained in the air. The principal constituents of the air are nitrogen and oxygen, which form respectively about four fifths and one fifth of its bulk. Besides these gases, however, the air contains water vapor, carbonic-acid gas, ammonia, argon in small quantities, and many other substances in still smaller quantities. For the purposes of this article it is only necessary to have in mind the nitrogen, oxygen, water vapor, and carbonic acid. Of these, the water vapor is easily converted into liquid, as, for example, in the formation of rain, while the other constituents are liquefied with difficulty. The name "liquid air" is applied to the substance that is obtained by converting the air as a whole into a liquid; but in this process the water and the carbonic acid become solid and can be filtered from the liquid so that the latter consists almost wholly of oxygen and nitrogen. A few years ago this liquid was obtainable in only very small quantities. To-day, thanks especially to the efforts of Mr. Charles E. Tripler, of New York, it can be produced in any desired quantity, and at moderate cost. In consequence of this, it has come to be talked about in a familiar way, and many persons have had the privilege of seeing and feeling it, and of learning something about its wonderful properties. The object of this article is to explain the method employed in the production of liquid air, to give an account of some of its properties, and to indicate some of the uses to which it may possibly be put.
In the older text-books of physics and of chemistry certain gases were classed as "permanent," under the impression that these could not be liquefied, and this impression was based upon the fact that all efforts to liquefy them had failed. A brief account of these efforts will be helpful.
Among the so-called permanent gases was chlorine. An English chemist, Northmore, first succeeded, early in this century, in liquefying chlorine. His work was, however, lost sight of, and in 1823 Faraday at the Royal Institution showed independently that this transformation of gaseous chlorine into the liquid can be effected comparatively easily. The method used by him is this: When chlorine gas is passed into cold water it forms with the water a solid product known as chlorine hydrate. If kept well cooled this hydrate can be dried. If then its temperature is raised even to the ordinary temperature of the room, the solid hydrate is decomposed into liquid water and gaseous chlorine. Faraday put some of the solid hydrate into a stout glass tube sealed at one end and bent at the middle. The other end of the tube was then closed. The tube was then suspended so that the two ends were turned downward. On gently warming the end in which was the solid hydrate, this was decomposed into chlorine and water. But the gas given off would under ordinary conditions have occupied a much larger space than the solid hydrate. Being prevented from expanding by the tube in which it was inclosed, it was under very considerable pressure. The end of the tube that was not warmed was cooled, and in this end, in consequence of the pressure and the comparatively low temperature, chlorine, which is gaseous under the ordinary pressure of the air, appeared as a liquid. The general method made use of by Faraday in this classical experiment is that which is always made use of for the purpose of liquefying gases, but for some gases pressures very much higher and temperatures very much lower are required. Faraday himself succeeded in liquefying all the gases then known except oxygen, hydrogen, nitrogen, nitric oxide, and marsh gas. He subjected oxygen to a pressure of about one thousand pounds to the square inch, or nearly seventy atmospheres, but it showed no signs of liquefaction. Later experimenters increased the pressure to four thousand pounds to the square inch, with no better results, so that it is not surprising that it came to be held that some gases are permanent.