The discovery that has made Professor Röntgen famous is, like many great discoveries, based upon the labours of other men in the same field. Geissler, whose vacuum tubes are so well known for their striking colour effects, had already noticed that electric discharges sent through very much rarefied air or gases produced beautiful glows. Sir William Crookes, following the same line of research, and reducing with a Sprengel air-pump the internal pressure of the tubes to 1/100000 of an atmosphere, found that a luminous glow streamed from the cathode, or negative pole, in a straight line, heating and rendering phosphorescent anything that it met. Crookes regarded the glow as composed of "radiant matter," and explained its existence as follows. The airy particles inside the tube, being few in number, are able to move about with far greater freedom than in the tightly packed atmosphere outside the tube. A particle, on reaching the cathode, is repelled violently by it in a straight line, to "bombard" another particle, the walls of the tube, or any object set up in its path, the sudden arrest of motion being converted into light and heat.
By means of special tubes he proved that the "radiant matter" could turn little vanes, and that the flow continued even when the terminals of the shocking-coil were _outside_ the glass, thus meeting the contention of Puluj that the radiant matter was nothing more than small particles of platinum torn from the terminals. He also showed that, when intercepted, radiant matter cast a shadow, the intercepting object receiving the energy of the bombardment; but that when the obstruction was removed the hitherto sheltered part of the glass wall of the tube glowed with a brighter phosphorescence than the part which had become "tired" by prolonged bombardment. Experiments further revealed the fact that the shaft of "Cathode rays" could be deflected by a magnet from their course, and that they affected an ordinary photographic plate exposed to them.
In 1894 Lenard, a Hungarian, and pupil of the famous Hertz, fitted a Crookes' tube with a "window" of aluminium in its side replacing a part of the glass, and saw that the course of the rays could be traced through the outside air. From this it was evident that something else than matter must be present in the shaft of energy sent from the negative terminal of the tube, as there was no direct communication between the interior and the exterior of the tube to account for the external phosphorescence. Whatever was the nature of the rays he succeeded in making them penetrate and impress themselves on a sensitised plate enclosed in a metal box.