The chrome tan is used only to a limited extent in the tanning of furs, the method requiring very careful treatment and accurate supervision during the various stages of the process, and the leather coming out colored a pale-blue-green tint, which for some purposes is objectionable. In some plants ponies and rabbits are tanned with chrome; and when the skins are to be dyed by means of certain coal tar dyes, they have to receive a chrome tannage. The leather produced by a chrome tan is very durable, and possesses great resistance to the action of water.
Any salt of chromium, with either mineral or organic acids, can be used, but chrome alum is the one most commonly employed. If a skin is entered directly into a solution of a chrome salt made basic with an alkali, the precipitation of the insoluble basic salt will take place very rapidly, and the tanning will be only superficial. The procedure is therefore first to treat the skins with a chrome solution which forms only small quantities of the basic salt. After the skins are impregnated with the solution, this is made basic, so that the real tan will take place within the skin tissues among the fibres of the corium. A common formula is the following: 5 lbs. of chrome alum are dissolved in 10 gallons of water. The skins are entered into the solution at about 70° F. and paddled for about 2 hours, or drummed for one hour. Then a solution of three pounds of washing soda is added slowly to the liquor which is then stirred up well, and the skins drummed or paddled again for an hour or two, and then left in the liquor for 12 to 24 hours till completely tanned. The skins are rinsed, and washed in 1/2% solution containing 2/3% of the weight of the skins of borax. The pelts are then well washed in clean water, hydro-extracted and dried.
Tanning by means of iron salts has thus far been merely a matter of scientific interest and has not found any practical use. The principle involved is identical with that of the preceding mineral processes.
The chamois dressing, as previously noted, is undoubtedly the oldest method of preparing leather from skin, the various fat-containing substances derived from animals, fish, birds, etc., being used for the purpose. The chief object of the fat was to coat the fibres of the skin, thus preventing their adhesion, and at the same time rendering them resistant to water. In the true chamois tan, the fat seems to have also a chemical function in contradistinction to the other which is merely physical or mechanical. For, if skins tanned by the chamois process be treated with a weak solution of an alkali, all the fatty materials should be removed thereby, but this happens only to a small extent, the pelt retaining its softness and pliability, and the other characteristic qualities of leather, indicating that the fat is combined intimately with the skin substance in a permanent fashion.