These laboratory diamonds burn in the air before the blowpipe to carbonic acid. In lustre, crystalline form, optical properties, density, and hardness they are identical with the natural stone.
In several cases Moissan separated ten to fifteen microscopic diamonds from a single ingot. The larger of these are about 0·75 mm. long, the octahedra being 0·2 mm.
The accompanying illustrations (Fig. 22) are copied from drawings in Moissan’s book _Le Four Electrique_.
Along with carbon, molten iron dissolves other bodies which possess tinctorial powers. We know of blue, green, pink, yellow, and orange diamonds. One batch of iron might contain an impurity colouring the stones blue, another lot would tend towards the formation of pink stones, another of green, and so on. Cobalt, nickel, chromium, and manganese, all metals present in the blue ground, would produce these colours.
I have long speculated as to the possibility of obtaining artificially such pressures and temperatures as would fulfil the above conditions. In their researches on the gases from fired gunpowder and cordite, Sir Frederick Abel and Sir Andrew Noble obtained in closed steel cylinders pressures as great as 95 tons to the square inch, and temperatures as high as 4000° C. According to a paper recently communicated to the Royal Society, Sir Andrew Noble, exploding cordite in closed vessels, has obtained a pressure of 8000 atmospheres, or 50 tons per square inch, with a temperature reaching in all probability 5400° Ab.
Here, then, we have conditions favourable for the liquefaction of carbon, and were the time of explosion sufficient to allow the reactions to take place, we should certainly expect to get the liquid carbon to solidify in the crystalline state.[7]
By the kindness of Sir Andrew Noble I have been enabled to work upon some of the residues obtained in closed vessels after explosions, and I have submitted them to the same treatment that the granulated iron had gone through. After weeks of patient toil I removed the amorphous carbon, the graphite, the silica,[8] and other constituents of the ash of cordite, and obtained a residue among which, under the microscope, crystalline particles could be distinguished. Some of these particles, from their crystalline appearance and double refraction, were silicon carbide; others were probably diamonds. The whole residue was dried and fused at a good red heat in an excess of potassium bifluoride, to which was added, during fusion, 5 per cent of nitre. (Previous experiments had shown me that this mixture readily attacked and dissolved silicon carbide; unfortunately it also attacks diamond to a slight degree.) All the operations of washing and acid treatment were performed in a large platinum crucible by decantation (except the preliminary attack with nitric acid and potassium chlorate, when a hard glass vessel was used); the final result was washed into a shallow watch-glass and the selection made under the microscope. The residue, after thorough washing and then heating in fuming sulphuric acid, was washed, and the largest crystalline particles picked out and mounted.