Carbonic acid, bisulphide of carbon, and sulphuretted hydrogen are impurities from which coal gas is freed before it is fit for use. By passing the gas over lime, the lime absorbs both the carbonic acid and the sulphuretted hydrogen; one per cent. of carbonic acid diminishes the illuminating power six per cent., and the sulphuretted hydrogen has an abominable smell.
The bisulphide of carbon, consisting of one equivalent of carbon and two of sulphur, is got rid of by passing the gas over hot lime. The water of the lime is decomposed, and carbonic oxide and sulphuretted hydrogen are produced; but the latter may be absorbed by passing the gas again over lime, or through a mixture of sawdust and the oxide of iron. The oxide of iron decomposes the sulphuretted hydrogen, forms water and sulphide of iron, then the air restores the sulphide to oxide, and the sulphur is deposited in the mixture. After passing the gas through it till none of that impurity remains, the gas is fit for use. The test is the nitro-prusside of sodium, which the gas stains purple if any of the impurity remains.
Paraffin, already mentioned as isomeric, is a pure hydrocarbon, colourless, transparent, and of crystalline texture. It melts at a heat of 120° or 130°, burns like wax without smell or smoke, and makes beautiful candles, which give a brilliant light on account of the 86 per cent. of carbon they contain. Paraffin oil is much used for lamps; the manufacture of these two substances at Bathgate is one of the largest chemical establishments in the world.
The black fœtid gas water resulting from the distillation of coals, formerly thrown away, is so rich in the salts of ammonia, that it has become the chief source from which these materials so important in the arts are obtained.
Ammonia is well known to be a colourless gas, with an acrid pungent smell, consisting of one equivalent of nitrogen and three of hydrogen. It has an alkaline character, combining with acids, and is extremely soluble in water.
Now the gas water contains carbonate of ammonia and sulphide of ammonium, and when any acid strong enough to decompose these substances is put into the liquid, the carbonic acid and sulphuretted hydrogen being volatile are driven off, and the acid combines with the ammonia to form a salt. For example, when muriatic acid is put into the liquid, it drives off the volatile gases and combines with the ammonia in solution to form muriate of ammonia, which is dissolved in water and evaporated till it crystallises; then it is vaporized and sublimed to free it from impurities.