The phenomena of slow combustion, as exhibited in certain states of the mine, by the Safety-lamp, are highly curious and interesting.
By suspending some coils of fine wire of platinum[37] above the wick of his lamp, the miner will be supplied with light in mixtures of fire-damp no longer explosive; for should his flame be extinguished by the quantity of fire-damp, the little coil of platinum will begin to glow with a light sufficiently bright to guide him in what would otherwise be impenetrable darkness, and to lead him into a purer atmosphere, when the heat thus increased will very frequently be sufficient to rekindle his lamp!
[37] Sir Humphry Davy attempted to produce the phenomena with various other metals, but he only succeeded with platinum and palladium; these bodies have low conducting powers, and small capacities for heat, in comparison with other metals, which seem to be the causes of their producing, continuing, and rendering sensible, these slow combustions.
In this case it will be readily perceived, that the combustion of the fire-damp is continued so slowly, and at so low a temperature, as not to be adequate to that ignition of gaseous matter which constitutes flame, although it excites a temperature sufficient to render platinum wire luminous.
Sir Humphry Davy observes, that there never can be any danger with respect to respiration, whenever the wire continues ignited; for even this phenomenon ceases when the foul air forms about two-fifths of the volume of the atmosphere.
The experiment, as originally performed by the illustrious chemist, is so interesting and instructive, that I shall here relate it in his own words.
"I introduced into a wire-gauze Safe lamp a small cage made of fine wire of platinum of one-seventieth of an inch in thickness, and fixed it by means of a thick wire of the same metal about two inches above the wick which was lighted. I placed the whole apparatus in a large receiver, in which, by means of a gas-holder, the air could be contaminated to any extent with coal gas. As soon as there was a slight admixture of coal gas, the platinum became ignited; the ignition continued to increase till the flame of the wick was extinguished, and till the whole cylinder became filled with flame; it then diminished. When the quantity of coal gas was increased, so as to extinguish the flame, at the moment of the extinction the cage of platinum became white hot, and presented a most brilliant light. By increasing the quantity of the coal gas still farther, the ignition of the platinum became less vivid: when its light was barely sensible, small quantities of air were admitted, its heat speedily increased; and by regulating the admission of coal gas and air, it again became white hot, and soon after lighted the flame in the cylinder, which as usual, by the addition of more atmospherical air, rekindled the flame of the wick."