It will be seen, from these instructions, that there should be a good assortment of wares from which to select. Economical firing cannot be managed if a burn be attempted whenever a piece is ready, and patience must be exercised so as to fill the kiln to advantage.
It is important that anyone attempting to burn a kiln should have some understanding of the phenomena of combustion. Many things occur in the firing which, without such an understanding, are not easily explained but which become perfectly clear when considered in the light of simple chemical science.
Combustion means oxidation or a combination between the elements of the fuel, principally carbon and hydrogen, and the oxygen of the air. This combination is a chemical action and as it proceeds heat is liberated. With a given amount of a specific fuel and a given amount of air there is always the same amount of heat, but the rate at which this heat is given off varies with the time occupied in the operation. Heat may be generated slowly which means a low temperature, or the same volume of heat may be generated rapidly, occupying a much shorter time and developing a higher temperature. From these statements it will be seen that there is a difference between heat and temperature; heat means volume, temperature means intensity. Thus the temperature derivable from a given amount of fuel depends upon the rapidity with which it is burned.
Combustion may be either complete or incomplete. In the former case enough air is supplied to oxidize all the fuel with, usually, some excess. The contents of the kiln are then bathed in the heated oxygen and the condition of the burning is called oxidizing. When the combustion is incomplete, on the other hand, there is a deficiency of oxygen. The kiln is charged with hot carbonaceous gases and smoke, and these, being hungry for oxygen, will abstract it from any substance which may be present. This condition is called reducing because the compounds which exist in clay or glaze are deprived of oxygen and thus reduced to a lower state of oxidation.
In burning a kiln one should be able to produce either of these conditions at will because there are certain wares which require one or the other in order to secure the best results. To put the matter in a nutshell, oxidizing conditions are induced by a strong draft and open flues, reducing conditions are obtained by closing the air inlets and using a liberal amount of fuel.