12. Now the way in which the Method of Least Squares is sometimes spoken of tends to conceal the magnitude of this distinction. Writers have regarded it as synonymous with the Law of Error, whereas the fact is that the two are not only totally distinct things but that they have scarcely even any necessary connection with each other. The Law of Error is the statement of a physical fact; it simply assigns, with more or less of accuracy, the relative frequency with which errors or deviations of any kind are found in practice to present themselves. It belongs therefore to what may be termed the physical foundations of the science. The Method of Least Squares, on the other hand, is not a law at all in the scientific sense of the term. It is simply a rule or direction informing us how we may best proceed to treat any group of these errors which may be set before us, so as to extract the true result at which they have been aiming. Clearly therefore it belongs to the inferential or logical part of the subject.

It cannot indeed be denied that the methods we employ must have some connection with the arrangement of the facts to which they are applied; but the two things are none the less distinct in their nature, and in this case the connection does not seem at all a necessary one, but at most one of propriety and convenience. The Method of Least Squares is usually applied, no doubt, to the most familiar and common form of the Law of Error, namely the exponential form with which we have been recently occupied. But other forms of laws of error may exist, and, if they did, the method in question might equally well be applied to them. I am not asserting that it would necessarily be the best method in every case, but it would be a possible one; indeed we may go further and say, as will be shown in a future chapter, that it would be a good method in almost every case. But its particular merits or demerits do not interfere with its possible employment in every case in which we may choose to resort to it. It will be seen therefore, even from the few remarks that can be made upon the subject here, that the fact that one and the same method is very commonly employed with satisfactory results affords little or no proof that the errors to which it is applied must be arranged according to one fixed law.

The Logic of Chance, 3rd edition — Part 39