The application, by Bunsen, of the _spectroscope_ to chemical analysis almost immediately resulted in his discovery, in 1860, of _cæsium_, and, in 1861, of _rubidium_. Cæsium was first detected in the mineral water of Dürkheim in the Palatinate and in the mineral petalite, by the two blue lines it forms in the spectrum, whence its name from the Latin _cæsius_, used to designate the blue of the clear sky. Rubidium was found in a lepidolite by means of a number of lines in different parts of the spectrum not previously observed, two being especially remarkable in the outermost region of the visible red portion—whence the name of the element from the Latin _rubidus_, used to designate the darkest red colour. The new metals were found to have the closest analogies to potassium, with which they usually occur associated in nature. Rubidium is found in a number of lepidolites, leucite, spodumene, triphylite, mica, and orthoclase, and in the Stassfurt carnallite; in sea-water and in many mineral waters. It occurs also in the ashes of many plants such as those of beetroot, tobacco, tea, coffee, etc. It is doubtful if it is a normal constituent of plant food, attempts to introduce it in place of potash having failed. It is not improbable that these elements would have remained unknown except for spectrum analysis. At all events, one of them—cæsium—was missed in 1846 by Plattner, in the course of the analysis of the mineral _pollucite_, in which it occurs to the extent of one third of its weight. After the discovery of cæsium by Bunsen, this mineral was again analysed by Pisani, when it was found that the alkali which Plattner had mistaken for potassium was in reality cæsium. Cæsium is found to a very small extent in many mineral waters, in a variety of minerals, and in the ashes of plants.
In 1861 Sir William Crookes made known the existence of a new element which he called _thallium_. He found it in a seleniferous deposit obtained from an oil of vitriol factory in the Harz. It was characterised by giving a bright green line in the spectroscope—whence its name from θαλλός, a green or budding twig. The discovery was confirmed in the following year by Lamy. Thallium, in its general chemical relations, has many analogies to the metals of the alkalis although in the metallic state it has the closest resemblance to lead. It occurs in many varieties of pyrites, in a few minerals, such as crookesite, lorandite, zinc-blende and copper pyrites, etc., and in certain mineral waters.