FORMATION OF IRON-ORES.—The iron-ores are another class of rocks which are formed only through the agency of organic matter. Iron is an abundant and wide-spread element in the earth’s crust, and, but for the intervention of life, we might say that, while there is iron everywhere, there is not much of it in any one place, since it is originally very thinly diffused. All rocks and soils contain iron, but it is mainly in the form of the peroxide, in which state it is entirely insoluble, and hence cannot be soaked out of the soil by the rain-water and concentrated by the evaporation of the water at lower levels in ponds and marshes, as a soluble substance like salt would be. If carried off with the sand and clay, by the mechanical action of water, it remains uniformly mixed with them, and there is no tendency to its separation and concentration so as to form a true iron-ore.
But what water cannot do alone is accomplished very readily when the water is aided by decaying organic matter, which is always hungry for oxygen, being, in the language of the chemist, a powerful reducing agent. The soil, in most places, has a superficial stratum of vegetable mould or half-decayed vegetation. The rainwater percolates through this and dissolves more or less of the organic matter, which is thus carried down into the sand and clay beneath and brought in contact with the ferric oxide, from which it takes a certain proportion of oxygen, reducing the ferric to the ferrous oxide. At the same time the vegetation is burned up by the oxygen thus obtained, forming carbon dioxide, which immediately combines with the ferrous oxide, forming carbonate of iron, which, being soluble under these conditions, is carried along by the water as it gradually finds its way by subterranean drainage to the bottom of the valley and emerges in a swamp or marsh.
Here one of two things will happen: If the marsh contains little or no decaying vegetation, then as soon as the ferrous carbonate brought down from the hills is exposed to the air it is decomposed, the carbon dioxide escapes, and the iron, taking on oxygen from the air, returns to its original ferric condition; and being then quite insoluble, it is deposited as a loose, porous, earthy mass, commonly known as bog-iron-ore, which becomes gradually more solid and finally even crystalline through the subsequent action of heat and pressure. When first deposited, the ferric oxide is combined with water or hydrated, and is then known as limonite (specimen No. 12); at a later period the water is expelled, and we call the ore hematite (specimen No. 13); and at a still later age it loses part of its oxygen, becomes magnetic and more crystalline, and is then known as magnetite (specimen No. 14). Thus it is seen that the iron-ores, as we pass from bog-limonite to magnetite, form a natural series similar to and parallel with that afforded by the coals as we pass from peat to graphite.