The fundamental vibrational interval of H$_{ 2}^+$ has been determined to be $\Delta G _{ 1/2} = 2191.126\,614(17)$ cm$^{ -1}$ by continuous-wave laser spectroscopy of Stark manifolds of Rydberg states of H$_2$ with the H$_{ 2}^+$ ion core in the ground and first vibrationally excited states. Extrapolation of the Stark shifts to zero field yields the zero-quantum-defect positions $-R_{ \textrm{ H}_2}$/$n^2$, from which ionization energies can be determined. Our new result represents a four-order-of-magnitude improvement compared to earlier measurements. It agrees, within the experimental uncertainty, with the value of 2191.126\,626\,344(17)(100) cm$^{ -1}$ determined in non-relativistic quantum electrodynamic calculations V. Korobov, L. Hilico and J.-Ph. Karr, Phys. Rev. Lett. 118, 233001 (2017) http://doi.org/10.1103/PhysRevLett.118.233001.
Categories: physics.atom-ph physics.chem-ph