The soaps formed from naphthenic acids have recently been investigated[8] and found to resemble the soaps made from cocoanut oil and palm kernel oil, in that they are difficult to salt out and dissociate very slightly with water. The latter property makes them valuable in textile industries when a mild soap is required as a detergent, e. g., in the silk industry. These soaps also possess a high solvent power for mineral oils and emulsify very readily. The mean molecular weight of naphthenic acids themselves is very near that of the fatty acids contained in cocoanut oil, and like those of cocoanut oil a portion of the separated acids are volatile with steam. The iodine number indicates a small content of unsaturated acids.
That naphthenic acids are a valuable soap material is now recognized, but except in Russia the soap is not manufactured to any extent at the present time.
The common alkali metals which enter into the formation of soap are sodium and potassium. The hydroxides of these metals are usually used, except in the so called carbonate saponification of free fatty acids in which case sodium and potassium carbonate are used. A water solution of the caustic alkalis is known as lye, and it is as lyes of various strengths that they are added to oils and fats to form soap. The density or weight of a lye is considerably greater than that of water, depending upon the amount of alkali dissolved, and its weight is usually determined by a hydrometer. This instrument is graduated by a standardized scale, and while all hydrometers should read alike in a liquid of known specific gravity, this is generally not the case, so that it is advisable to check a new hydrometer for accurate work against one of known accuracy. In this country the Baumé scale has been adopted, while in England a different graduation known as the Twaddle scale is used. The strength of a lye or any solution is determined by the distance the instrument sinks into the solution, and we speak of the strength of a solution as so many degrees Baumé or Twaddle which are read to the point where the meniscus of the lye comes on the graduated scale. Hydrometers are graduated differently for liquids of different weights. In the testing of lyes one which is graduated from 0° to 50° B. is usually employed.