[19] It is chiefly a mixture of carbonic oxid, and hydrogen gas.
These observations also apply to the distillation of tar, which when distilled either in a vaporous or nascent state, during its first production from coal in the ordinary process, or if it be submitted to a second distillation, mingled with a fresh portion of pit-coal, a practice usually had recourse to when this product cannot be disposed of more advantageously. The best depth of coal in the retort for procuring excellent gas, and at the same time for yielding the greatest quantity from the same weight in the shortest possible time, is about six inches.
The brightness of the coal-gas flame is rather diminished when the gas has been long kept over water, and hence for illumination it should be used as soon as prepared, but of course properly purified.
The quantity of gas taken up by water is affected by temperature, because the temperature increases its elasticity; the quantity of gas absorbed, diminishes as the temperature increases, and increases as the temperature diminishes. ½7 part of its own bulk of pure coal-gas is absorbed by the water over which it is confined in the gazometer.
The chemical constitution of this gazeous fluid is best ascertained by burning it in a vessel of oxygen gas, over lime-water in a pneumatic reservoir, by means of a bladder and bent brass pipe. Two products are then obtained, viz. water and carbonic acid. That water is produced, may be shown by burning a very small stream of the gas in a long funnel-shaped tube open at both ends. The formation of carbonic acid is evinced, by the copious precipitation of the lime-water in the foregoing experiment.
If carburetted hydrogen be mixed with a sufficient quantity of oxygen gas or common air and fired by the electric spark, or by any other method, an explosion takes place more or less violent according to the quantity of carbonaceous matter condensed in the hydrocarbonat; and the remaining gas consists of carbonic acid, together with any unconsumed gas, or excess of oxygen, whilst the water condenses in drops on the sides of the vessel. A few cubic inches of the mixed airs is as much as can be conveniently managed at a single explosion; and when any portion of olefiant gas is present, even this quantity will endanger very thick glass jars. A very vivid red flame appears at the moment of the explosion, and a great enlargement takes place in an instant, after which the bulk is suddenly reduced to much less than the original quantity. When the carbonic acid is absorbed by lime-water, if the gasses have been properly proportioned, no gazeous residue is left, except accidental impurities. Though carburetted hydrogen gas, is sometimes naturally produced in coal-mines, and occasionally mixes with common air, producing dreadful explosions, yet when coal-gas is mixed with common air, it does not explode unless the gas be to the air as 1 to 10 nearly. Such are the leading chemical habitudes of this gazeous product. The varieties of carburetted hydrogen gas all agree in being inflammable; but they possess this property in various degrees, as is evinced by the variable brightness of the flame which they yield when set on fire.