The electronic ground state for Lithium is $1s^22s$, and not $1s^22p$. The traditional argument for why this is so is based on a screening argument that claims that the $2p$ electron is better shielded by the $1s$ electrons, and therefore higher in energy then the configuration that includes the $2s$ electron. We show that this argument is flawed, and in fact the actual reason for the ordering is because the electron-electron interaction energy is higher for the $2p-1s$ repulsion than it is for the $2s-1s$ repulsion.
Categories: physics.atom-ph cond-mat.str-el