The ore deposits of northwestern and southern Illinois were formed so many millions of years ago that it is possible to propose only theories of their origin. Most geologists think that the minerals, dissolved in warm or hot water, came from deep in the earth. Perhaps the mineral-bearing water came from, or was associated with, rocks that were or had been molten (igneous rocks), but it may have had some other source. Why the ores occur where we now find them is not fully known. The cooling of the solutions and the lessening of pressure as the solutions rose toward the surface may have had a part in ore deposition. Faults and the nature of the rocks encountered by the depositing solutions also appear to have had an influence.
Although Illinois is not usually thought of as a mining state, northwestern and southern Illinois together produced in 1963 nearly $5,000,000 worth of zinc, about $600,000 worth of lead, and $6,500,000 worth of fluorspar. The annual total value is about $12,000,000.
The southern Illinois fluorspar district has another distinction—for many years its mines have been the major domestic source of the nation’s fluorspar.
About 450,000,000 years ago, a shallow ocean covered Illinois. Its waves and currents carried clean white sand and deposited it as curving beaches, sand bars, and dunes. This sand differed from many sands in that it was composed almost exclusively of grains of the mineral quartz instead of being a mixture of quartz and other minerals.
Quartz is composed of silica (SiO₂), and sands such as the ancient Illinois sand that are composed of quartz are known as silica sands. Quartz is very hard and will scratch glass and some steel. Perfect quartz crystals, which are rare, are longer than they are thick and end in pyramids. Probably not many grains of the ancient sand came from perfect crystals; they more likely resulted from the decaying and breaking down of rocks such as granite, which are mixtures of quartz grains and other mineral particles.
The quartz grains probably did not come directly from their source to Illinois. Instead, it is likely they first were deposited elsewhere and formed into sandstone. That sandstone was subsequently broken down by weathering agents and the grains transported to the ancient Illinois sea by streams.