Herein we report on the reactivity between palladium, Pd, and the MAX phases, Ti${ _2}$AlC, Ti${ _3}$AlC${ _2}$, Ti${ _3}$SiC${ _2}$ and Cr${ _2}$AlC. Diffusion couples of Pd/MAX were heated to 900 { \deg}C under uniaxial stress of ~20 MPa for 2, 4, and 10 h in a vacuum (<1 Pa) hot press. The diffusion couples were examined using X-ray diffraction, scanning electron microscopy and energy-dispersive X-ray spectroscopy. After heating to 900 { \deg}C for 10 h, the diffusion layer thicknesses in the Ti${ _2}$AlC/Pd, Cr${ _2}$AlC/Pd, Ti${ _3}$AlC${ _2}$/Pd and Ti${ _3}$SiC${ _2}$/Pd couples were found to be 35, 45, 105 and 410 mm, respectively. Thus, Ti${ _2}$AlC is the most resistant to reaction, while Ti${ _3}$SiC${ _2}$ is least resistant, with Cr${ _2}$AlC and Ti${ _3}$AlC${ _2}$, in between. In all cases, the reaction occurred by the diffusion of the A-group element into Pd, concomitant with Pd diffusion into the MAX phase. No diffusion of the M and X atoms was detected.
Categories: cond-mat.mtrl-sci