665 grams pure aluminum sulphate, or 948 grams potassium alum, are dissolved in 1 liter of hot water. 1137 grams of lead acetate (sugar of lead) are also dissolved in 1 liter of hot water.
The two solutions are mixed, and thoroughly stirred. A heavy white precipitate forms, which is filtered off, and discarded after the solution has cooled. The aluminum acetate is contained in the filtrate, and the solution is brought to a density of 10 degrees Beaumé by the addition of water, if necessary, and is preserved for use in this form.
Ferrous sulphate, iron vitriol, or copperas, as it is commonly known, forms pale green crystals, which on exposure to air lose water, and crumble down to a white powder. It is very soluble in both cold and hot water, but the solutions oxidize very rapidly, turning yellowish, and should therefore be used immediately. Care must be taken that a good quality of iron vitriol be used for the mordant, otherwise very unsatisfactory results will be obtained.
Ferrous acetate is prepared in a manner similar to the aluminum acetate, and is occasionally employed instead of the ferrous sulphate. Inasmuch, however, as the solution of ferrous acetate is very easily oxidizable when exposed to the air, a more stable form is used, and this comes on the market as iron pyrolignite or iron liquor. This can be prepared by dissolving iron in crude acetic or pyroligneous acid, or by treating a solution of iron sulphate with calcium pyrolignite. Iron liquor is really a solution of ferrous acetate that contains certain organic impurities which prevent, or rather, considerably retard the oxidation of the iron salt, but which in no way interfere with its mordanting properties. The commercial product can be had in various concentrations, but 10 degrees Beaumé is the most usual and most convenient.
The most important copper salts used in fur dyeing processes are copper sulphate, or blue vitriol, occurring in large blue crystals, very soluble in cold and in hot water; and copper acetate, which is formed by treating a solution of copper sulphate with a solution of the requisite quantity of lead acetate. Copper acetate can also be obtained in the form of blue-green crystals, very soluble in water, the solution becoming turbid on prolonged heating, due to the formation of a greenish basic copper acetate. This insoluble compound is known commonly as verdigris, although it is not usually produced in the manner mentioned. Numerous fur dyeing formulas contain verdigris, but inasmuch as the basic copper acetate is insoluble and thus incapable of reacting with any of the substances used in dyeing, it is assumed that the soluble normal copper acetate was meant, for this compound is also sometimes called verdigris.