The glaze which had been brought to perfection by the Chinese at an early period differs from all those yet mentioned by its hardness, its high fusing-point, and in its chemical composition. Speaking generally, the glaze of porcelain differs in composition from the paste which it covers only sufficiently to allow of its becoming completely liquid at the extreme heat of the furnace; and just as the paste of Chinese porcelain has a wider limit of variability than that made in Europe, but is on the whole of a ‘milder’ type than the latter, so we find that while the glazes of the Chinese are as a whole less refractory and not quite so hard, there is still a wide range of variation in these qualities.
If, then, we theoretically regard porcelain as a compound of a silicate of alumina with an alkaline silicate of the same base, we may say that the glaze of porcelain is formed by the latter body alone, that it is, in fact, merely a fused felspar. But as in the case of the paste, so in the glaze there is generally present an excess of silica, derived from the quartz contained in the petuntse or pegmatite, and this silica enters into combination with some other bases which are present in the constituents of the glaze, thereby increasing its fusibility and modifying the contraction in cooling. The most important of these additional bases is lime, so that the more fusible type may be called a calcareous, as opposed to a more refractory or purely felspathic glaze. As much as 21 per cent. of lime has been found in some Chinese glazes, the amount of alumina being proportionately reduced.
There is more or less lime in the glaze of most kinds of European hard porcelain, but the exceptionally hard and refractory paste made at Sèvres since the time of Brongniart is covered by a glaze of corresponding hardness from which that earth is absent. This hard paste has, however, of late been replaced in part by one of a milder type, and with this latter a calcareous glaze has been adopted even at Sèvres, the object of the change being, as we have said, to allow of a more brilliant decoration.
There is a perceptible difference in the aspect of these two types of glazes after firing. The hard, non-calcareous glaze has a slightly milky look. The softer calcareous type is more brilliant, and approaches in transparence and limpidity to the lead glazes of soft porcelain. A glaze of this last kind was used at Sèvres for a few years after the first introduction of the hard paste, and perhaps also at Dresden in quite early days.