The principal objection to a hard refractory glaze, such as that so long in use at Sèvres, arises from the difficulty of properly incorporating the enamel colours with its body. The restriction of the number of pigments that can be employed, both under and on the surface of the glaze, in consequence of the high temperature at which the latter melts, is another drawback. The dulness, the ‘painted on’ look of so much of the decoration on European hard paste porcelain, is in great measure a consequence of the employment of a glaze that is only softened at a high temperature. As an example of a medium type of glaze we give the composition of that used at Berlin in 1836. This consisted of kaolin, 31 per cent.; quartz, 43 per cent.; gypsum, 14 per cent.; and ground porcelain, 12 per cent. A glaze long in use at Dresden is of a very similar character. Felspar, it will be seen, does not enter into its composition, and such a glaze can contain but little potash or soda. With this we may contrast the hard glaze of Sèvres, composed simply of ground pegmatite, a rock consisting mainly of felspar. This glaze yields on analysis 74 per cent. of silica, 17 per cent. of alumina, and as much as 8 per cent. of potash.
The glaze on Chinese porcelain is prepared by mixing certain special varieties of petuntse with an impure lime, prepared by burning limestone with dry fern as fuel. It contains, as we have seen, from 15 to 21 per cent. of lime, 5 to 6 per cent. of alkalis, 11 per cent. of alumina, and 66 per cent. of silica.
We give these examples to illustrate the principal types of glazes used for hard paste porcelain. It will be noticed that the constituents are drawn from widely different sources.
The glazes of soft paste porcelain always contain a large amount both of lead and of potash or soda, so that they approximate in composition to a flint glass. The alkalis, generally introduced as carbonates, necessitate a previous fritting of part at least of the materials. Boracic acid plays an important part in the glaze of most modern English wares: it is generally introduced in the form of borate of soda or borax. This acid replaces in part the silica, just as in the paste the glassy materials are replaced by bone-earth.