Water drops sliding on hydrophobic surfaces spontaneously separate charges at their rear. It is unclear how this charge separation affects the contact angles of a sliding drop. We slide grounded and insulated drops on hydrophobic surfaces at low capillary numbers (\leq 10^{ -4}). We find that drop charge leads to spontaneous electrowetting, which decreases the contact angles. Additionally, the deposited charges lead to a surface charge effect and decrease the contact angle. Both phenomena compensate each other at the receding contact line, resulting in an insignificant change in the receding contact angle of a sliding drop.
Categories: physics.flu-dyn cond-mat.soft