There has been no response from Russia or separatist leaders in Ukraine to Ukrainian President Petro Poroshenko's request for a new round of talks on Saturday.
Poroshenko said he suggested a time and place for the talks during a phone call with European Union foreign policy chief Catherine Ashton. He said he is waiting for the other side to confirm.
The EU and United States have threatened Russia with more sanctions if Moscow and the pro-Russian fighters in eastern Ukraine do not take steps to de-escalate the crisis.
The fighting has picked up since Ukraine ended a unilateral cease-fire earlier this week.
Ukrainian forces claim they retook a village Friday in the rebel-held region of Slovyansk, one of the hot spots of the fighting.
Earlier Friday, Poroshenko, German Chancellor Angela Merkel and French President Francois Hollande discussed the situation in eastern Ukraine in a three-way phone call.
Merkel discussed the Ukraine crisis with President Barack Obama in a telephone call Thursday.
On Wednesday, the foreign ministers of Ukraine, Russia, France and Germany met in Berlin and said talks aimed at resuming a cease-fire between the Ukrainian military and pro-Russian rebels should begin no later than Saturday.
Last month, separatist leaders met with Ukrainian ex-president Leonid Kuchma as Kyiv's representative. Moscow's ambassador to Kyiv and members of the Organization for Security and Cooperation in Europe (OSCE) also attended the talks in the eastern Ukrainian city of Donetsk.
President Poroshenko declared a unilateral, week-long cease-fire June 20 and then extended it by three days. Citing lack of cooperation from rebels, he refused a second extension and ordered the resumption of military operations on Tuesday.
The Ukrainian president told Vice President Joe Biden in a phone conversation Thursday he was ready to return to a cease-fire as soon as it can be confirmed that both sides are observing it. He also said a cease-fire was contingent on all hostages being released and control over the Ukrainian-Russian border being established, with monitoring by the OSCE.
Fighting continues in eastern Ukraine, with the press center of Kyiv's "anti-terrorist operation" reporting that nine Ukrainian servicemen had been killed and 13 wounded in battles with separatist forces on Friday as of 2 p.m. local time.
Also Friday, Ukraine's Foreign Ministry sent a note of protest to Moscow over what it called "regular gross violations of Ukrainian airspace" by Russia. It detailed what it said were several separate incidents on Thursday in which Russian military helicopters flew over Ukrainian territory
The secretary of Ukraine's National Security and Defense Council, Andriy Parubiy, said Friday that if Russian aircraft violate Ukrainian airspace again, they will be shot down.